Changing all the user data folders & paths

Hi I need some help with a slight problem.

I have just got a new Win7 64bit desktop system which has the OS and some applications installed onto a 40GB Sold State Drive which is the C: drive.
Naturally, there is now not a lot of room on it but have a 1TB drive (E:) which so far only has a couple of applications otherwise it is almost empty.

My question is how can I change all the user data and non critical folders & paths to use E: instead of C: as the default location?
I am listed on the computer as a member of the Administrators Group.

Can anybody help me here as I am a newbie to Win 7.


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