Run as Administrator Problems

I have configured my system with an Administrator and two standard user accounts.

Some programs installed for all users under Administrator ask for administrator password each time they are executed from the user's account even when the "Run as Administrator" check box is ticked in the user's shortcut properties.

I am also having the same problem with shortcuts placed in the all user's Startup folder for unregistered standalone applications like Real Temp. Ticking the "Run as Administrator" does not cause the application to run automatically at user startup or logon. I have also attempted to run this a scheduled task at logon but it fails to run under any account other that when the Admin is logged on.

How can I fix these problems?

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