Windows 7 Block Access to Certain Programs

I'm trying to install this game onto my computer. (I've got Windows 7 Ultimate 64 Bit) Every time I click to run the .exe I either get that Windows cannot find the specified path, or that I don't have permission to run the program. I'm the administrator on my PC so I don't understand why I don't have access to run this program. If anyone could help, I would greatly appreciate it.

Thanks in Advance


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