netsh isn't very robust. You won't be able to reorder them. What you will want to do is remove all the entries and re-add them.
netsh interface ipv4 delete dnsservers "Local Area Connection" 10.91.201.56
..57
..55
..54
then re-add in the order you want
netsh interface ipv4 add dnsservers "Local Area Connection" <address> index=#