Default "Save To" and Libraries on Users Network Drive

We are in the process of rolling out Windows 7 Pro machines, into a brand new network. All users have an S: drive and are supposed to be saving all their data there for server based backup. How do I make Win 7 save to S: by default, move the Libraries to S: and therefore protect the users data.

I've done some digging and it looks like a nightmare. I'm sure I'm not the first with this question, can someone point me to a simple but proper solution please.


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