1 yes its possible
2 you want a fresh install of Windows 10 first before adding W11
3 once you have Windows installed how you want it go into the disk manager and tell it not to assing a letter to the unallocated 100G you plain to install the other system on
note exturnal usb drives are not an option here it must be internal drive space and you may want to consider a upgrade/ new drive before starting
4 install Windows to the unallowocated 100g drive... then tell it not to allowcate a letter to the drive the other system has as it C
once thats done you pick which system boots by default and how many seconds you want it to wait for you to imput a change before doing so and your dual boot is finished until Microsoft hacks into your computer and tries to auto update everything
option b
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buy a swap drive bay and put your two drives in it... this allows you to physically block Microsoft [or anyone else] changing your system while its not conected and you don't need to worry about dual booting because only one of the drives is in the system at any given time... its a bit more unusual looking but ultimately less tecky to use and again most the time only one system is wanted so you only change when needed [does help with backup recovery of files]