Go to Open
Action Center->All Settings->System->Display and make sure that under the
MULTIPLE DISPLAYS, you have it set to
"EXTEND THESE DISPLAYS". Your video card should do the rest. I just tested this on my dell desktop PC, and am watching Deep Space Nine on Netflix via Edge full screen on my primary 24"monitor, while looking at MSN.com and reading news full screen on my 2nd monitor, a 20" display running Chrome. I also keep my Google Calendar up on that 2nd monitor for checking dates while E-mailing, making Hotel and travel reservations, etc. It works great!
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