Windows 7 Saving Custom Paint Colors

Maybe this can't be done, does anybody know where the file for default colors is stored. Maybe I could
modify one.
Z
 
I tried to do it and they always seemed to disappear. I did not, however, save a file where the custom color was used. I would assume, it would be saved with that file.

If you can't do anything else, write down the numbers for your color so you can get it back quickly.
 
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