Yes, it is possible to configure Windows so you can have both your Ethernet adapter and WiFi adapter enabled and route all local traffic (subnet 255.255.255.0) to Ethernet and anything else via WiFi.
Here are the steps on how to do it:
- Open the Windows Control Panel.
- Click on Network and Sharing Center.
- Click on Change adapter settings on the left-hand side.
- Right-click on your Ethernet adapter and select Properties.
- Click on the Advanced tab.
- In the Advanced Settings dialog box, scroll down to the Routing section.
- Check the box next to Use default gateway on remote subnet.
- Click on OK to close the Advanced Settings dialog box.
- Repeat...