There are only three firewall profiles 'Domain', 'Private' and 'Public' and they are tied to the network you are connected to. You can have multiple associated to each firewall profile. Just as an FYI lot's of applications, including Windows updates, use port 443 so the built in firewall won't be able to isolate just web traffic. For email you just need to look in the account settings and see what ports are being used for SMTP and either POP or IMAP (secure or not)