The first question: is the problem with the actual charging activity or with what Windows reports? Ignoring what Windows shows, do the charger and battery do what they are supposed to? You describe the charging LED coming on when you plug in the charger. Does the battery charge completely and hold its charge? Do both batteries do that? Also, is the new battery an OEM battery or one from a third party (I've had extremely bad luck with replacement batteries from third parties).
Given that you have an end-of-life original battery, a new battery of a different capacity (and unknown quality?), two chargers with different voltages, and mixed results being reported by Windows, my initial inclination would be to discount a bad driver as...