All permissions combine, the only permission that blocks other is a Deny.
Lets say you have a user George, which is in the Administrators Group. If George has Read Only access to file X but Administrators have Write access, George now has read/write access.
Please note there is a difference between "Administrator" and "Administrators".
Administrator would refer to a user account named Administrator, Administrators is a group which contains all the users who are members of the Administrators group.