Hi
I know that it is recommended that you have Widows XP installed first.
I've done it this way several times with no problems.
But since you are computer aware...
The other option might be to disconnect the drive with Windows 7 on it.
Install Widows XP on the other drive, and then use EasyBCD to set the boot setup to dual boot.
EasyBCD - Free software downloads and software reviews - CNET Download.com
I'm guessing that when you plug the Windows 7 drive back in it will boot to it, because it will be first in line, in the bios.
Then allow you to use EasyBCD to add XP to the boot menu.
Disclaimer: I have never done this myself, but I don't see why it wouldn't work.
Mike
Ps. I have found almost nothing that would't run in...