Mystery solved - I think
Not 100% sure yet given it's only been a couple of days, but after a horrendous day on Sunday where the system shutdown repeatedly almost every time it was restarted over a period of a couple of hours, I decided to disconnect a USB hub just to see whether it was having any effect, and incredibly since then all has run perfectly.
Given it appeared to be a hardware rather than a software issue, and as the power supply which was the only contender for the title really wasn't overheating or seemingly likely to be the culprit, and because to replace it was going to cost a cool £50 at least, I really wanted to ensure I'd looked at all the other possibilities, and the hub was the 1st on the list.
So I'm...