You can invoke the menu bar in windows explorer by simply pressing the alt key on your keyboard. To make that particular menu bar available all the time, choose the drop down arrow next to "Organize" and choose "Layout" and select menu bar.
As far as changing the location of some of your folders in Win7, don't use the links from the start menu or the libraries folder, rather use the actual location C:\Users\YourUserName choose the folder your want to move/relocate, right click and choose properties, use the location tab and the move button to relocate them where you want them.