We seem to have things that might be a little confusing.
Drives are not set as active, partitions are. You cannot set a drive as active in the bios, just set its priority in the boot process.
The partition Windows boots into for the OS is usually C: and the others will change accordingly. I have seen situations where a drive was cloned and problems arose from the Drive lettering, but you should not have that situation.
But don't worry about the drive letters, after you get the SSD set up, shutdown and add the other drive. When you start up again, it should boot fine. The old c: partition will be visible, but with a different drive letter. If not, let us know...