Hi Julio,
It appears that this partition is an EFI System Partition in W10 and it's needed to boot your computer into W10. Here's a link explaining why it needs to be there:
What is an EFI system partition?
I believe this partition was always there, and you just stumbled upon the new 100MB drive partition while doing Maintenance on your bootdrive. Since this is a required System Partition needed by W10 to boot windows, it certainly is
NOT a good idea to try to clean off files from this partition, defrag them, or lock them, or encrypt them, or compress them!!

You should not be doing anything with this Partition for any conceivable reason.
That being said, we could use a little more information about the computer you are using here on W10. Is this a desktop PC or a laptop? Is it an OEM computer (Dell, HP, Acer, Toshiba, etc.)? Or is it a self-built PC or custom-built PC you built yourself from parts or paid a professional Tech to build for you? If it's an OEM computer, please provide us with Make/Model. If it's a self-built or custom-built PC, please provide Make/Model of your Motherboard, RAM memory sticks, GPU card, CPU chip, and PSU Make/Model/Wattage.
If you don't have this information handy, get as much as you can and you can download the free
SPECCY diagnostic program from piriform.com. Download
SPECCY and run it and post the result output text file back here for our further analysis.
Basically, I think you reported something as a problem that's not really a problem, simply part of the normal W10 system file structure that you were unaware of BEFORE. Be advised that W10 has more system partitions than W7 and can up to 12 partitions on your C: bootdrive. If you haven't fooled around with W10 you would most likely be unaware of this.
In any case, I noticed also that you appear to have a secondary hard drive in your computer, the D: drive, and from what we see we cannot tell if it's an internally connected drive (one that connects to a connector port physically on the Mobo via SATA, eSATA, etc. or via a USB port). In either case, I would recommend that you disconnect that 2nd drive from your computer, and make sure that W10 boots ok. If it does, you can power down, and reconnect that drive to your computer and everything should continue working normally.
Best,
<<<BIGBEARJEDI>>>