Hi and thank you both for the in-depth solutions. 
Trouble i followed the directions on the link you provided and it has worked to an extent (ill explain in a sec).
 acurasd my network is slightly complex, a static IP approach is good provided i can see the other devices, though my knowledge is limited when it comes to networks. Currently i have a British ISP called Be Broadband that supply a router with teh subscription - its a Thomson Speedtouch wireless router 
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My network consists of a MacBook Pro running OSX 10.5.8 -Leopard (wireless) and a NAS drive (wired) 
Link Removed - Invalid URL Configuring all these to work well together is always a hassle but i have succeeded in the past with WinXP Pro. I am currently using Win7 Home Premium.
After following the registry tutorial to change secpol provided by Trouble i have been able to setup and access shared documents on my Pc via my Mac. However i read another post claiming that by default Win7 cannot see more than 1 network device and followed a registry tweak to work around this. Though i must point out that after doing so it caused havoc with my Bit Defender antivirus systray icon and had to do a system restore which luckily got me back to square1. 
Read more on that reg tweak here >> 
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Currently my network shows the macbook but not the NAS drive, when i try to browse my network it simply doesn't find anything else. So i am now detahced from my main work share, any thoughts on this?